Material Safety Data Sheet according to 1907/2006/EC, Article 31 1Identification of substance
· Product details · Trade name Aidol FIC
· Article number: 2028
· Application of the substance / the preparation Wood treatment · Manufacturer/Supplier:
Remmers Baustofftechnik GmbHPostfach 1255D-49624 Löningen / GermanyTel.: 05432/83-0Fax: 05432/3985
· Informing department:
Product Safety department: Tel.: +49 (0)5432/83-138/-538 E-Mail: sales@remmers.co.uk
· Emergency information:
during working hours:U.K.: Tel.: +44 (0) 845 373 0103Far East: Tel.: +65( 0) 67410277Head Office Germany: Tel.: +49 (0)5432 83 185after working hours: Tel.: +49 (0)171/6428-297
2Hazards identification
· Hazard designation:
Xn HarmfulN Dangerous for the environment
· Information pertaining to particular dangers for man and environment
The product has to be labelled due to the calculation procedure of the "General Classification guideline forpreparations of the EU" in the latest valid version. R 22
May cause sensitisation by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
· Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technicalliterature and by information furnished by supplier companies. 3Composition/information on ingredients
· Chemical characterization
· Description: solvent-based wood preservative with biocide actival ingredient · Dangerous components: Material Safety Data Sheet according to 1907/2006/EC, Article 31 Trade name Aidol FIC
· Additional information For the wording of the listed risk phrases refer to section 16. 4First aid measures
· After inhalation
Take affected persons into the open air and position comfortablySeek medical treatment in case of complaints.
· After skin contact If skin irritation continues, consult a doctor.
· After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.
· After swallowing
Do not induce vomiting. Do not give anything to drink. Call a doctor immediately!Keep the person affected quiet.
· Information for doctor
· The following symptoms may occur:
In case of prolonged/repeated exposure or in high concentrations:HeadacheDizzinessDry skinExcessive contact with skin, eyes or respiratory system may cause irritation.
· Danger
Long-term or repeated exposure may cause inflammation of the skin (dermatitis). Swallowing followed by vomiting may lead to aspiration into the lungs which leads to suffocation or toxicpulmonary oedema.
· Treatment
symptomatic treatmentTo avoid dermatitis (skin inflammation), use skin cream. 5Fire fighting measures
· Suitable extinguishing agents
FoamWater spray jetWater mistDry extinguishing agents, carbon dioxide, sand or earth should only be used for small fires.
· Special hazards caused by the material, its products of combustion or flue gases:
May be released in case of fireCarbon monoxide (CO)(in case of incomplete combustion)Carbon dioxideFormation of toxic gases is possible during heating or in case of fire. Vapours are heavier than air and spread out over the ground. Ignition over greater distances is possible.
· Protective equipment:
Wear full protective suit. Wear self-contained breathing apparatus.
· Additional information
Cool endangered containers with water spray jet. Collect contaminated fire fighting water separately. It must not enter drains. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. 6Accidental release measures
· Person-related safety precautions: Material Safety Data Sheet according to 1907/2006/EC, Article 31 Trade name Aidol FIC
· Measures for environmental protection:
Do not allow to enter the ground/soil. Prevent from spreading (e.g. by confining or oil barrier). Inform responsible authorities in case product reaches bodies of water or sewage system. Dilute with plenty of water.
· Measures for cleaning/collecting:
Send for recovery or disposal in suitable containers. Place leaking containers in a marked drum or recovery drum. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
· Additional information: See Section 13 for information on disposal. 7Handling and storage
· Handling
· Information for safe handling: Use only in well ventilated areas.
· Information about protection against explosions and fires:
Fumes can combine with air to form an explosive mixture.
· Storage
· Requirements to be met by storerooms and containers: No special requirements.
· Information on storage in a common storage facility:
Suitable material for containers and pipes: Light metals and their alloys.
· Further information about storage conditions:
Store container in a well ventilated position. Protect from frost. Do not smoke in storage areas. Storage temperature: room temperature. Keep container tightly closed. 8Exposure controls and personal protection
· Additional information about design of technical systems: Use only in well-ventilated areas. · Components with limit values that require monitoring at the workplace: 34590-94-8 (2-methoxymethylethoxy)propanol OES Long-term value: 308 mg/m³, 50 ppm 111-76-2 2-butoxyethanol OES Short-term value: 50 ppm
· Additional information: The lists that were valid during compilation were used as a basis. · Personal protective equipment
· General protective and hygienic measures
Do not eat, drink or smoke while working. Apply solvent-resistant skin protection preparation before beginning work. Keep away from food, beverages and animal feed. Immediately remove soiled, saturated clothing. Wash hands before pauses and after work. Avoid contact with eyes. Avoid contact with eyes and skin.
· Respiratory equipment:
In case vapours/aerosols develop:Short term filter device:Filter A/P2.
· Protection of hands: Impervious gloves
· Material of gloves Nitrile rubber, NBR Material Safety Data Sheet according to 1907/2006/EC, Article 31 Trade name Aidol FIC
· Eye protection: Tightly sealed safety glasses.
· Body protection: Protective work clothing. 9Physical and chemical properties:
· General Information
· Change in condition Melting point/Melting range: Boiling point/Boiling range:
· Flash point:
· Self-inflammability:
· Danger of explosion:
· Explosive Limits:
· Vapour pressure at 20°C:
· Density at 20°C
· Solubility in / Miscibility with
· Distribution coefficient (n-octanol/water): white spirit · Viscosity: kinematic at 20°C:
· Solvent content: Organic solvents: 10 Stability and reactivity
· Thermal decomposition / conditions to be avoided:
No decomposition if handled and stored according to specifications. Avoid: heat, flames, sparks
· Materials to be avoided: Strong oxidising agents
· Dangerous reactions No dangerous reactions known
· Dangerous decomposition products:
None if stored properly. None if used properly. 11 Toxicological information
· Acute toxicity: · LD/LC50 values that are relevant for classification: 34590-94-8 (2-methoxymethylethoxy)propanol Oral Material Safety Data Sheet according to 1907/2006/EC, Article 31 Trade name Aidol FIC 112-34-5 2-(2-butoxyethoxy)ethanol Oral 55406-53-6 3-Iodo-2-propynylbutylcarbamate Oral
Inhalative LC50/4 h 6.89 mg/l (Ratte) 52645-53-1 permethrin (ISO) Oral
· Primary irritant effect:
· on the skin: Dries skin out.
· on the eye: Irritating effect.
· Sensitisation: No sensitising effect known.
· Experience with humans:
Frequent or longer lasting skin contact may degrease and dry out skin which may lead to skin irritation andinflammation (dermatitis). Causes eye discomfort, however, no damage to eye tissue is possible. After swallowing and subsequent vomiting, aspiration into the lungs may occur which leads to suffocation ortoxic lung oedema.
· Additional toxicological information:
The product shows the following dangers based on the calculation method of the General EC ClassificationGuidelines for Preparations as issued in the latest version:Irritant
· Sensitisation May cause sensitisation by skin contact. 12 Ecological information:
· Information on elimination (persistence and degradability):
· Other information:
Data for 2-methoxy-methylethoxy-propanol:Degree of elimination: > 70%Test method: OECD 302B/ ISO 9888/ EEC 88/302, C OECD 301E/ EEC 84/449, C.3Analysis method: DOC reductionEvaluation: easily eliminated, readily biodegradableData for permethrin:Rapid degradation in the ground where the "half-life" is usually less than 4 weeks. Degradation products arefurther degraded to carbon dioxide.
· Behaviour in environmental systems:
· Mobility and bioaccumulation potential:
Date for permethrin:Neither permethrin nor its degradation products are freely mobile in the ground.
· Ecotoxical effects:
· Acquatic toxicity:
· Type of test Effective concentration Method Assessment
Data for 3-iodine-2-propinylbutylcarbamate: Toxicity for fish:Rainbow trout: LC-50: 0.124 mg/l/96 hBluegill sunfish: LC-50: 0.5 mg/l/96 hLiterature source: Microbicides for the Protection of Materials, Wilfried Paulus
· Remark: Toxic for fish
· Behaviour in sewage processing plants:
· Type of test Effective concentration Method Assessment
Data for 2-(2-butoxyethoxy)ethanol:Toxicity for bacteria:Ps. putida EC-10 1170 mg/l/18h Bringmannn-Kühn-Test
Material Safety Data Sheet according to 1907/2006/EC, Article 31 Trade name Aidol FIC
· General notes:
Water danger class 3 : extremely hazardous to water. Do not allow product to reach ground water, bodies of water or sewage system, even in small quantities. Hazardous to drinking water even if extremely small quantities leak into soil. Also toxic for fish and plankton in bodies of water. Toxic for aquatic organisms
13 Notes on disposal:
· Product:
· Recommendation
Do not dispose of together with household garbage. Do not allow product to reach sewage system. The given refuse codes are recommendations based upon the intended use of the product. Because ofspecial use and disposal conditions at the user´s, other codes may apply under other conditions.
· European waste catalogue
03 00 00 WASTES FROM WOOD PROCESSING AND THE PRODUCTION OF PANELS AND
03 02 00 wastes from wood preservation03 02 02 organochlorinated wood preservatives
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
· Recommended cleaning agent: Water, if necessary with cleaning agent. 14 Transport information
· Maritime transport IMDG/GGVSea:
· Marine pollutant: No · Transport/Additional information: Not a hazardous good according to the above regulations. 15 Regulatory information
· Designation according to EC guidelines:
Observe normal safety precautions for handling chemicalsThe product has been classified and labelled in accordance with EC Guidelines / Ordinance on HazardousMaterials (GefStoffV)
· Code letter and hazard designation of product:
Xn HarmfulN Dangerous for the environment
· Hazard-determining components of labelling:
· Risk phrases:
May cause sensitisation by skin contact.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
· Safety phrases:
Keep away from food, drink and animal feedingstuffs.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
37/39 Wear suitable gloves and eye/face protection. Material Safety Data Sheet according to 1907/2006/EC, Article 31 Trade name Aidol FIC
Avoid release to the environment. Refer to special instructions/safety data sheets.
· Product Code: HSM-LV 30
· National regulations · Technical instructions (air): Class Proportion in %
· Water hazard class:
Water danger class 3: extremely hazardous to water. according to appendix 4 VwVwS
· Other regulations, limitations and prohibition ordinances
Do not use this wood preservative on wood that could come in direct contact with food or animal feed. Wood preservatives contain biocidal ingredients to protect wood from pests. They should only be usedaccording to directions and only in the approved areas where protective measures are required. Misuse may harm your health and the environment. Only for use in professional facilities. Application only on load bearing and bracing woodelements. Cover treated wood dust-tight forwards livingspaces and rooms where people gather. This also applies forroof structures, if they will be used as living space. Active ingredients: 7,5% IPBC 0,32% deltamethrin
· Professional Association (BG) Code of Practice: M 050 "Handling harmful substances" 16 Other information:
This data is based on our present state of knowledge. However, it does not constitute a guarantee for anyspecific product features and does not establish a legally valid contractual relationship. Delivery specifications are found in the respective Technical Information Sheets.
· Relevant R-phrases
20/22 Harmful by inhalation and if swallowed. 22
May cause sensitisation by skin contact.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 53
May cause long-term adverse effects in the aquatic environment.
· Department issuing data specification sheet: Product Safety department
Tribunal d'appel en Tribunal matière de permis APPEAL UNDER SECTION 50(1) OF THE HIGHWAY TRAFFIC ACT , R.S.O. 1990, c. H.8, FROM A DECISION OF THE REGISTRAR OF MOTOR VEHICLES PURSUANT TO SECTION 47(1) OF THAT ACT CARMICHAEL, Agent representing the Applicant KYLE BIEL, Agent representing the Registrar of Motor Vehicles DECISION AND REASONS This is an appeal to the Licence
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