Chemwatch australian msds 22-0444

DY-MARK P10;P20;P30 PAINTMARKER PEN
Chemwatch Independent Material Safety Data Sheet
Issue Date: 10-Jun-2010
CHEMWATCH 22-0444
Version No:2.0
CD 2010/2 Page 1 of 6
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
DY-MARK P10;P20;P30 PAINTMARKER PEN
PROPER SHIPPING NAME
FLAMMABLE LIQUID, N.O.S.(contains n-propanol)
PRODUCT USE
Marker pen contains maximum 30 ml ink. Information on this MSDS refers to ink sealed in this marker pen, however, it applies to these inks in bulk.
The inks are contained in capillary or valve reservoirs and will not spill or leak under normal conditions.
SUPPLIER
Company: Dy- Mark Pty Ltd
Address:
89 Formation Street
Wacol
QLD, 4076
Australia
Telephone: +61 7 3271 2222
Fax: +61 7 3271 2751
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.
POISONS SCHEDULE
None
RISK
Risk Codes
• HARMFUL- May cause lung damage if swallowed.
• Vapours may cause drowsiness and dizziness.
SAFETY
Safety Codes
• Do not breathe gas/fumes/vapour/spray.
• Wear suitable protective clothing.
• Use only in well ventilated areas.
• Keep container in a well ventilated place.
• To clean the floor and all objects contaminated by thismaterial use water and detergent.
• Keep away from food drink and animal feeding stuffs.
• If swallowed IMMEDIATELY contact Doctor or PoisonsInformation Centre. (show this container or label).
• This material and its container must be disposed of ashazardous waste.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
other ingredients determined not to be hazardous Section 4 - FIRST AID MEASURES
SWALLOWED
• - If swallowed do NOT induce vomiting.
- If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
- Observe the patient carefully.
continued.
DY-MARK P10;P20;P30 PAINTMARKER PEN
Chemwatch Independent Material Safety Data Sheet
Issue Date: 10-Jun-2010
CHEMWATCH 22-0444
Version No:2.0
CD 2010/2 Page 2 of 6
Section 4 - FIRST AID MEASURES
- Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
- Avoid giving milk or oils.
- Avoid giving alcohol.
- If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible aspiration of vomitus.
EYE
• If this product comes in contact with the eyes:
- Immediately hold eyelids apart and flush the eye continuously with running water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower
lids.
- Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
- Transport to hospital or doctor without delay.
SKIN
• If skin contact occurs:
- Immediately remove all contaminated clothing, including footwear.
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
INHALED
• - If fumes or combustion products are inhaled remove from contaminated area.
- Lay patient down. Keep warm and rested.
- Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
- Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained.
Perform CPR if necessary.
NOTES TO PHYSICIAN
• Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or pharmacologically.
To treat poisoning by the higher aliphatic alcohols (up to C7):
-
Gastric lavage with copious amounts of water.
- It may be beneficial to instill 60 ml of mineral oil into the stomach.
- Oxygen and artificial respiration as needed.
- Electrolyte balance: it may be useful to start 500 ml. M/6 sodium bicarbonate intravenously but maintain a cautious and conservative attitudetoward electrolyte replacement unless shock or severe acidosis threatens.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
• - Alcohol stable foam.
- Dry chemical powder.
- BCF (where regulations permit).
- Carbon dioxide.
FIRE FIGHTING
• - Alert Fire Brigade and tell them location and nature of hazard.
- May be violently or explosively reactive.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water course.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by
FIRE/EXPLOSION HAZARD
• - Liquid and vapour are flammable.
- Moderate fire hazard when exposed to heat or flame.
- Vapour forms an explosive mixture with air.
- Moderate explosion hazard when exposed to heat or flame.
Combustion products include: carbon monoxide (CO), carbon dioxide (CO2), other pyrolysis products typical of burning organic material.
FIRE INCOMPATIBILITY
• - Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result.
HAZCHEM
•3Y
Personal Protective Equipment
Chemical splash suit.
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
• - Remove all ignition sources.
- Clean up all spills immediately.
- Avoid breathing vapours and contact with skin and eyes.
- Control personal contact by using protective equipment.
continued.
DY-MARK P10;P20;P30 PAINTMARKER PEN
Chemwatch Independent Material Safety Data Sheet
Issue Date: 10-Jun-2010
CHEMWATCH 22-0444
Version No:2.0
CD 2010/2 Page 3 of 6
Section 6 - ACCIDENTAL RELEASE MEASURES
MAJOR SPILLS
• - Clear area of personnel and move upwind.
- Alert Fire Brigade and tell them location and nature of hazard.
- May be violently or explosively reactive.
- Wear breathing apparatus plus protective gloves.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
• - Containers, even those that have been emptied, may contain explosive vapours.
- Do NOT cut, drill, grind, weld or perform similar operations on or near containers.
- DO NOT allow clothing wet with material to stay in contact with skin.
- Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of overexposure occurs.
- Use in a well-ventilated area.
- Prevent concentration in hollows and sumps.
SUITABLE CONTAINER
• - Packing as supplied by manufacturer.
- Plastic containers may only be used if approved for flammable liquid.
- Check that containers are clearly labelled and free from leaks.
- For low viscosity materials (i) : Drums and jerry cans must be of the non-removable head type. (ii) : Where a can is to be used as an inner package,
the can must have a screwed enclosure.
- For materials with a viscosity of at least 2680 cSt. (23 deg. C)
- For manufactured product having a viscosity of at least 250 cSt. (23 deg. C)
- Manufactured product that requires stirring before use and having a viscosity of at least 20 cSt (25 deg. C).
STORAGE INCOMPATIBILITY
• Alcohols
- are incompatible with strong acids, acid chlorides, acid anhydrides, oxidising and reducing agents.
- reacts, possibly violently, with alkaline metals and alkaline earth metals to produce hydrogen
- react with strong acids, strong caustics, aliphatic amines, isocyanates, acetaldehyde, benzoyl peroxide, chromic acid, chromium oxide, dialkylzincs,
dichlorine oxide, ethylene oxide, hypochlorous acid, isopropyl chlorocarbonate, lithium tetrahydroaluminate, nitrogen dioxide, pentafluoroguanidine,
phosphorus halides, phosphorus pentasulfide, tangerine oil, triethylaluminium, triisobutylaluminium
- should not be heated above 49 deg. C. when in contact with aluminium equipment.
STORAGE REQUIREMENTS
• - Store in original containers in approved flammable liquid storage area.
- Store away from incompatible materials in a cool, dry, well-ventilated area.
- DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
- No smoking, naked lights, heat or ignition sources.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source
PERSONAL PROTECTION
RESPIRATOR
Type A Filter of sufficient capacity
EYE
• - Safety glasses with side shields.
- Chemical goggles.
- Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the
wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption
for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and
suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon
as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after
workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
• - Wear chemical protective gloves, eg. PVC.
- Wear safety footwear or safety gumboots, eg. Rubber.
Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: such as:
- frequency and duration of contact,
- chemical resistance of glove material,
- glove thickness and
continued.
DY-MARK P10;P20;P30 PAINTMARKER PEN
Chemwatch Independent Material Safety Data Sheet
Issue Date: 10-Jun-2010
CHEMWATCH 22-0444
Version No:2.0
CD 2010/2 Page 4 of 6
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
OTHER
• - Overalls.
- PVC Apron.
- PVC protective suit may be required if exposure severe.
- Eyewash unit.
- Some plastic personal protective equipment (PPE) (e.g. gloves, aprons, overshoes) are not recommended as they may produce static electricity.
- For large scale or continuous use wear tight-weave non-static clothing (no metallic fasteners, cuffs or pockets), non sparking safety footwear.
The local concentration of material, quantity and conditions of use determine the type of personal protective equipment required. For furtherinformation consult site specific CHEMWATCH data (if available), or your Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
• For flammable liquids and flammable gases, local exhaust ventilation or a process enclosure ventilation system may be required. Ventilation
equipment should be explosion-resistant.
Air contaminants generated in the workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of fresh
circulating air required to effectively remove the contaminant.
solvent, vapours, degreasing etc., evaporating from tank (in still air).
aerosols, fumes from pouring operations, intermittent container filling, low speedconveyer transfers, welding, spray drift,plating acid fumes, pickling (released at lowvelocity into zone of active generation)direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts,gas discharge (active generation into zone ofrapid air motion) Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Pens containing flammable liquid; does not mix with water.
PHYSICAL PROPERTIES
Liquid.
Does not mix with water.
Floats on water.
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
• - Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerisation will not occur.
For incompatible materials - refer to Section 7 - Handling and Storage.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
• HARMFUL- May cause lung damage if swallowed.
continued.
DY-MARK P10;P20;P30 PAINTMARKER PEN
Chemwatch Independent Material Safety Data Sheet
Issue Date: 10-Jun-2010
CHEMWATCH 22-0444
Version No:2.0
CD 2010/2 Page 5 of 6
Section 11 - TOXICOLOGICAL INFORMATION
• Risk of serious damage to eyes.
• Vapours may cause dizziness or suffocation.
• Vapours may cause drowsiness and dizziness.
TOXICITY AND IRRITATION
• Not available. Refer to individual constituents.
N-PROPANOL:• unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
Eye (rabbit): 4 mg Open SEVEREEye (rabbit): 20 mg/24h Moderate • The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produceconjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form ofdermatitis is often characterised by skin redness (erythema) and swelling the epidermis.
SKIN
n- propanol
Section 12 - ECOLOGICAL INFORMATION
This material and its container must be disposed of as hazardous waste.
Ecotoxicity
Ingredient
Section 13 - DISPOSAL CONSIDERATIONS
• - Containers may still present a chemical hazard/ danger when empty.
- Return to supplier for reuse/ recycling if possible.
Otherwise:- If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.
- Where possible retain label warnings and MSDS and observe all notices pertaining to the product.
Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their area.
A Hierarchy of Controls seems to be common - the user should investigate:- Reduction.
- DO NOT allow wash water from cleaning or process equipment to enter drains.
- It may be necessary to collect all wash water for treatment before disposal.
- In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
- Where in doubt contact the responsible authority.
- Recycle wherever possible.
- Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified.
- Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or Incineration in a licenced apparatus (after admixture with suitable combustible material).
- Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.
Section 14 - TRANSPORTATION INFORMATION
HAZCHEM:
•3Y
ADG7:
Class or division:
continued.
DY-MARK P10;P20;P30 PAINTMARKER PEN
Chemwatch Independent Material Safety Data Sheet
Issue Date: 10-Jun-2010
CHEMWATCH 22-0444
Version No:2.0
CD 2010/2 Page 6 of 6
Section 14 - TRANSPORTATION INFORMATION
Special packingprovisions:Shipping Name:FLAMMABLE LIQUID, N.O.S. (contains n-propanol) Land Transport UNDG:
Class or division:
Shipping Name:FLAMMABLE LIQUID, N.O.S. (contains n-propanol) Air Transport IATA:
ICAO/IATA Class:
Shipping Name: FLAMMABLE LIQUID, N.O.S. *(CONTAINS N-PROPANOL) Maritime Transport IMDG:
IMDG Class:
Shipping Name: FLAMMABLE LIQUID, N.O.S.(contains n-propanol) Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
None
REGULATIONS
Regulations for ingredients
n-propanol (CAS: 71-23-8) is found on the following regulatory lists;
"Australia Exposure Standards","Australia Hazardous Substances","Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of
Chemical Substances (AICS)","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","IMO
MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk","IMO Provisional Categorization of Liquid Substances - List 2: Pollutant
only mixtures containing at least 99% by weight of components already assessed by IMO","OECD Representative List of High Production Volume (HPV)
Chemicals"
No data for Dy-Mark P10;P20;P30 PaintMarker Pen (CW: 22-0444)
Section 16 - OTHER INFORMATION
• Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references.
• The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700. Issue Date: 10-Jun-2010Print Date: 10-Jun-2010

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